University of Florida since Jan 1999
Professor
Max-Planck Institute of Metals Research 1993 - 1998
Deputy Director
Education:
University of Heidelberg 1982 - 1988
Diplom, Chemistry
Skills:
Materials Science Nanotechnology Characterization Spectroscopy Nanomaterials Research Scanning Electron Microscopy Chemistry University Teaching Experimentation Science Physics Afm Semiconductors Design of Experiments Diversity and Inclusion
The invention relates to a method for producing a solid molded article, in particular a ceramic and/or metallic article made of pulverized particles. The invention also relates to stable dispersions of pulverized particles in an aqueous fluid medium, solid molded articles made of pulverized particles, and sintered ceramic and/or metallic molded articles.
Photocatalytic Nanocomposites And Applications Thereof
Wolfgang M. Sigmund - Gainesville FL, US Sung-Hwan Lee - Seoul, KR Benjamin Koopman - Gainesville FL, US Brij Moudgil - Gainesville FL, US Georgios Pyrgiotakis - Gainesville FL, US Vijay Krishna - Gainesville FL, US
Assignee:
University of Florida Research Foundation, Inc. - Gainsville FL
International Classification:
A62D 3/00 A62D 3/17 A62D 3/10 B01J 37/00
US Classification:
588299, 588301, 588306, 502129
Abstract:
A photocatalyst nanocomposite which can be used to destroying biological agents includes a carbon nanotube core, and a photocatalyst coating layer covalently or ionically bound to a surface of the nanotube core. The coating layer has a nanoscale thickness. A method of forming photocatalytic nanocomposites includes the steps of providing a plurality of dispersed carbon nanotubes, chemically oxidizing the nanotubes under conditions to produce surface functionalized nanotubes to provide C and O including groups thereon which form ionic or covalent bonds to metal oxides, and processing a metal oxide photocatalyst sol-gel precursor in the presence of the nanotubes, wherein a nanoscale metal oxide photocatalyst layer becomes covalently or ionically bound to the nanotubes.
Wolfgang M. Sigmund - Gainesville FL, US Joachim Spatz - Heidenheim, DE
Assignee:
University of Florida Research Foundation, Inc. - Gainesville FL
International Classification:
B32B 29/00
US Classification:
4282951, 4282974, 4282981, 428403, 428500, 427212
Abstract:
Ultralyophobe interfaces that are substantially inert to contaminants, thereby resulting in surfaces that are hydrophobic and/or lyophobic. The substrates include a substrate surface and have a bonding layer and a plurality of flexible fibers bound to the bonding layer. The flexible fibers have an elastic modulus and an aspect ratio, wherein as the elastic modulus of the fiber increases, the aspect ratio increases such that the flexible fibers bend upon contact of a liquid surface.
Ceramic Nanofibers For Liquid Or Gas Filtration And Other High Temperature (> 1000° C.) Applications
Wolfgang M. Sigmund - Gainesville FL, US Vasana Maneeratana - Gainesville FL, US Paolo Colombo - Padua, IT Chang-Yu Wu - Gainesville FL, US Hyoungjun Park - Gainesville FL, US Qi Zhang - Gainesville FL, US
Assignee:
Univesity of Florida Research Foundation, Inc. - Gainesville FL
In accordance with the invention there are devices and processes for making ceramic nanofiber mats and ceramic filters for use in high temperature and in corrosive environments. The process for forming a ceramic filter can include electrospinning a preceramic polymer solution into a preceramic polymer fiber having a diameter from about 10 nm to about 1 micron and forming a preceramic polymer fiber web from the preceramic polymer fiber onto a collector. The process can also include pyrolyzing the preceramic polymer fiber web to form a ceramic nanofiber mat having a diameter less than the diameter of the preceramic polymer fiber, the ceramic nanofiber mat comprising one or more of an oxide ceramic and a non-oxide ceramic such that the ceramic fiber mat can withstand temperature greater than about 1000 C.
Joining Of Ceramic Powder Pressed Components In The Green Or Sintered State With A Gelcast Joint
Amit Daga - Gainesville FL, US Wolfgang Sigmund - Gainesville FL, US
International Classification:
C03B029/00
US Classification:
156089110, 156089160
Abstract:
A method of joining components includes the steps of providing a slurry including a solvent, a ceramic, metal or cermet powder and at least one binder selected from natural monomers or cross linkable polymer compositions. The binder is crosslinked to form a gel. The gel is then placed between the first and at least a second component to be joined. The gel is then sintered to form an article having a gelcast joint binding the first and second components. The resulting joint region will generally have the same strength as the first and second components.
Nanoparticles For Protection Of Cells From Oxidative Stress
Wolfgang M. Sigmund - Gainesville FL, US Yi-Yang Tsai - Brandon FL, US Ioannis Constantinidis - Gainesville FL, US Jenny Dorley - Gainesville FL, US Carol Ann Sweeney - Micanopy FL, US Nicholas Edward Simpson - Alachua FL, US Mark A. Atkinson - Gainesville FL, US
Assignee:
UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. - GAINESVILLE FL
International Classification:
A61K 9/14 A61K 35/12 A61K 33/24
US Classification:
424489, 424 937, 424617, 435375, 977773, 977904
Abstract:
The present invention concerns metal oxide semiconductor nanoparticles with free radical scavenging activity, compositions comprising such nanoparticles, methods for their use, and methods for their production. In one aspect, the invention concerns a method for enhancing the survival or viability of transplanted cells, comprising administering an effective amount of metal oxide semiconductor nanoparticles to a target anatomical site of a subject before, during, or after administration of transplant cells to the subject. Preferably, the metal oxide nanoparticle is a cerium oxide (ceria) nanoparticle.
A composite hybrid coating having a thick highly transparent hard coating with excellent barrier properties is described. The hybrid coating is the gelled dispersion of nanoparticles in a sol with least one hydrolyzable silane and at least one hydrolyzable metal oxide precursor. In one embodiment a composite hybrid coating is formed by the curing of a dispersion formed by the addition of a suspension of boehmite nanoplatelets in a sol prepared by the hydrolysis of tetraethoxysilane, γ-glycidoxypropyltrimethoxysilane and titanium tetrabutoxide in ethanol. A plastic substrate can be coated with the dispersion and the dispersion gelled to a thickness of at least 5 μm with heating to less than 150 C.
Transparent Inorganic-Organic Hybrid Materials Via Aqueous Sol-Gel Processing
A sol to form an inorganic-organic hybrid coating having a thick highly transparent hard coating is described. The hybrid coating is formed from a combined aqueous sol with least one hydrolyzable silane and at least one hydrolyzable metal oxide precursor where the only organic solvents present are those liberated upon hydrolysis of the silanes and metal oxide precursors. In one embodiment an inorganic-organic hybrid coating is formed by combination of a sol, prepared by the hydrolysis of tetraethoxysilane and γ-glycidoxypropyltrimethoxysilane with an excess of water, and a sol, prepared by the hydrolysis of titanium tetrabutoxide and γ-glycidoxypropyltrimethoxysilane with a deficiency of water. A plastic substrate can be coated with the combined sol and the combined sol gelled to a thickness of at least 5 μm with heating to less than 150 C.