A process is disclosed of forming a reversal dye image. This is accomplished by developing an imagewise exposed photographic element with a black-and-white developer and poisoning the developed silver as a redox amplification catalyst for a peroxide oxidizing agent. The undeveloped silver is then rendered developable to form a silver catalyst image pattern. This latter silver image pattern is then used to catalyze the redox reaction of a peroxide oxidizing agent and a dye-image-generating reducing agent, such as a color-developing agent, or a redox dye-releaser.
Redox Amplification Process Employing A Combination Of Oxidizing Agents
My invention is directed to a process of forming dye images. I accomplish this through a first redox amplification reaction in which a cobalt (III) complex oxidizing agent enters into a redox reaction with a reducing agent at the site of a catalyst image. A second redox amplification reaction follows in which a peroxide oxidizing agent is employed along with dye-image-generating reducing agent to form a dye image corresponding to the pattern of the catalyst.
Process Of Bleaching Silver Images To Form Dye Images Using Cobalt Complexes And Peroxides
My invention is directed to a process of forming dye images. I accomplish this by bleaching a silver image at least in part with a cobalt bleaching agent to form within the silver image pattern an immobile cobalt reaction product. The concurrent presence of the immobile cobalt reaction product, a peroxide oxidizing agent and a dye-image-generating reducing agent within the silver image pattern allows a dye image to be formed which corresponds to the silver image pattern.
Processing Compositions Comprising Inert Transition Metal Complex Oxidizing Agents And Reducing Agents
An improvement is provided in processes wherein an oxidation-reduction reaction is utilized to form an image. In one aspect of this invention, the improvement comprises employing an oxidizing agent and a reducing agent which undergo imagewise redox reaction in the presence of catalytic material, the oxidizing agent and the reducing agent being so chosen that the reaction products are noncatalytic for the oxidation-reduction reaction. In another aspect of this invention, a substitution inert metal complex is utilized as the oxidant in oxidation-reduction, image-forming processes. Novel processing compositions and photographic materials are also described.
Imagewise Hardening With Inert Transition Metal Complex Oxidizing Agents
An improvement is provided in processes wherein an oxidation-reduction reaction is utilized to form an image. In one aspect of this invention, the improvement comprises employing an oxidizing agent and a reducing agent which undergo imagewise redox reaction in the presence of catalytic material, the oxidizing agent and the reducing agent being so chosen that the reaction products are noncatalytic for the oxidation-reduction reaction. In another aspect of this invention, a substitution inert metal complex is utilized as the oxidant in oxidation-reduction image-forming processes. Novel processing compositions and photographic materials are also described. In a specific aspect, this divisional application relates to processes for tanning a crosslinkable colloid with the reaction products of the above redox reaction.
Reversal Imaging Process Including Redox Amplification
A process is disclosed of forming a reversal dye image. This is accomplished by developing an imagewise exposed photographic element with a black-and-white developer and poisoning the developed silver as a redox amplification catalyst for a peroxide oxodizing agent. The undeveloped silver is then rendered developable to form a silver catalyst image pattern. This latter silver image pattern is then used to catalyze the redox reaction of a peroxide oxidizing agent and a dye-image-generating reducing agent, such as a color-developing agent, or a redox dye-releaser.
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