Provided is a process for preparing an at least bis-carbamate functional 1,3,5-triazine by contacting an at least diamino-1,3,5-triazine, an acyclic organic carbonate and a base, as well as certain novel compositions producible thereby. Also provided are substantially halogen contamination free crosslinker compositions comprising the products obtainable by the process, and curable compositions based upon these crosslinkers.
Process For The Preparation Of A Crosslinker Composition
This invention is directed to a process for the preparation of a crosslinker composition, comprising the steps of providing a mixture of an aliphatic alcohol A having at least one hydroxyl group and from 1 to 10 carbon atoms, with at least one multifunctional aldehyde C having at least two aldehyde groups —CHO to form a mixture AC, heating the mixture AC to convert at least a part of the multifunctional aldehyde C to its hemiacetal or to its acetal to form a mixture (AC)′, adding to the mixture (AC)′ least one cyclic urea U or the educts to produce the said cyclic urea U in situ, which cyclic urea U has at least one unsubstituted >NH group, and reacting the mixture thus obtained to form a chemical bond between the nitrogen atom of the at least one unsubstituted >NH group of the at least one cyclic urea U5 and the carbon atom of the least one aldehyde group —CHO of the multifunctional aldehyde C, and coating compositions comprising the said crosslinker composition.
Lawrence A. Flood - Norwalk CT Ram B. Gupta - Bronx NY Revathi Iyengar - Peekskill NY David A. Ley - New Canaan CT Vankatarao K. Pai - Stamford CT
Assignee:
Cytec Technology Corp. - Wilmington DE
International Classification:
C07D25148
US Classification:
544204
Abstract:
Provided is a novel carbamate functional 1,3,5-triazine of the general formula ##STR1## wherein Z' is selected from the group consisting of hydrogen, hydrocarbyl, and a group represented by the formula NHQ', each Q' is independently selected from the group consisting of a hydrocarbyl, a hydrocarbyloxy hydrocarbyl and a group represented by the formula COOY, with the proviso that at least two of the Q' groups are COOY, and each Y is independently selected from the group consisting of a hydrocarbyl group and a hydrocarbyloxy hydrocarbyl ether group, with the proviso that at least one Y group is a hydrocarbyloxy hydrocarbyl ether group. These carbamate functional 1,3,5-triazines find use, for example, as crosslinkers or reactive modifiers in curable compositions.
1,3,5-Triazine Carbamates From Amino-1,3,5-Triazines And Organic Carbonates And Curable Compositions Thereof
Lawrence A. Flood - Norwalk CT Ram B. Gupta - Bronx CT Revathi Iyengar - Peekskill CT David A. Ley - New Canaan CT Venkatarao K. Pai - Stamford CT
Assignee:
Cytec Technology Corporation - Wilmington DE
International Classification:
C07D25148 C08G 1880
US Classification:
544196
Abstract:
Provided is a process for preparing an at least bis-carbamate functional 1,3,5-triazine by contacting an at least diamino-1,3,5-triazine, an acyclic organic carbonate and a base, as well as certain novel compositions producible thereby. Also provided are substantially halogen contamination free crosslinker compositions comprising the products obtainable by the process, and curable compositions based upon these crosslinkers.
Carboxylated Amino-1,3,5-Triazines, Derivatives Thereof And Processes For Preparing The Same
Lawrence Allen Flood - Norwalk CT Ram Baboo Gupta - Bronx NY
Assignee:
Cytec Technology Corp. - Stamford CT
International Classification:
C07D25140 C07D24142 C07D25148 C07D25154
US Classification:
544194
Abstract:
The present invention relates generally to carboxylated amino-1,3,5-triazines and the preparation thereof via carboxylation of amino-1,3,5-triazines with carbon dioxide and a base. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, and particularly carbamate and isocyanate functional 1,3,5-triazines. The present invention also relates to the preparation of such carbamate and isocyanate functional 1,3,5-triazines.
Carboxylated Amino-1,3,5-Triazines, Derivatives Thereof And Processes For Preparing The Same
Lawrence Allen Flood - Norwalk CT Ram Baboo Gupta - Bronx NY
Assignee:
Cytec Technology Corp. - Wilmington DE
International Classification:
C07D25154
US Classification:
544194
Abstract:
The present invention relates generally to carboxylated amino-1,3,5-triazines and the preparation thereof via carboxylation of amino-1,3,5-triazines with carbon dioxide and a base. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, and particularly carbamate and isocyanate functional 1,3,5-triazines. The present invention also relates to the preparation of such carbamate and isocyanate functional 1,3,5-triazines.
Processes For Preparing Isocyanate Functional 1,3,5-Triazines And Derivatives Thereof
Lawrence Allen Flood - Norwalk CT Ram Baboo Gupta - Bronx NY
Assignee:
Cytec Technology Corp. - Stamford CT
International Classification:
C07D25140 C07D25142 C07D25148 C07D25154
US Classification:
544194
Abstract:
The present invention relates generally to carboxylated amino-1,3,5-triazines and the preparation thereof via carboxylation of amino-1,3,5-triazines with carbon dioxide and a base. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, and particularly carbamate and isocyanate functional 1,3,5-triazines. The present invention also relates to the preparation of such carbamate and isocyanate functional 1,3,5-triazines.
Carboxylated Amino-1,3,5 Triazines And Derivatives Thereof
Lawrence Allen Flood - Norwalk CT Ram Baboo Gupta - Bronx NY
Assignee:
Cytec Technology Corp. - Wilmington DE
International Classification:
C07D25140 C07D25142 C07D25148 C07D25154
US Classification:
544194
Abstract:
The present invention relates to carboxylated amino-1,3,5-triazines represented by the formula: ##STR1## wherein Z and Z. sup. 1 are independently selected from the group consisting of hydrogen, a hydrocarbyl, a hydrocarbyloxy and a group represented by the formula --N(Q). sub. 2 ; each Q is independently selected from the group consisting of hydrogen, a hydrocarbyl and a group Y, with the proviso that no more than one Q in each --N(Q. sub. 2) is Y; and Y is selected from the group consisting of a carboxyl group and a carboxylate salt group. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, particularly carbamate and isocyanate functional 1,3,5-triazines. The so-produced derivatives may find use as, for example, crosslinking agents in curable compositions.
2012 to 2000 Quality Control/Quality Assurance Technician DynCorp InternationalTechnical Inspectors Fort Benning, GA 2011 to 2012 Materiel Readiness Officer/Maintenance ManagerITT Corporation
2007 to 2011 Quality System ManagerITT Industries
2005 to 2007 Quality Control Analyst SupervisorITT Industries
2001 to 2001 Warehouse Specialist Lesco as a sub-contractorFayetteville Technical Community College
1999 to 2001 StudentJ.T. Davenport & Sons Distribution Center Sanford, NC 1998 to 1999 Warehouse ManagerJ.T. Davenport & Sons Distribution Center Sanford, NC 1994 to 1998 Shipping SupervisorUnited States Army
1974 to 1994 First Sergeant
Isbn (Books And Publications)
Unions And Public Policy: The New Economy, Law, And Democratic Politics