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An exhaust control system for an automotive internal combustion engine having an exhaust system that includes a NO adsorber to trap and reduce NO emissions from the engine. The engine is operated using an air/fuel ratio that alternates between lean and rich, with the adsorber storing NO during the lean periods of combustion and catalytically reducing the NO during the rich periods of combustion. The system determines the amount of NO stored in the adsorber using upstream and downstream O sensors. The release of stored NO and O at the beginning of the rich regeneration causes a delay between switching of the sensors. The system determines how much of this delay is due to the release of stored O and subtracts that amount from the total delay. There is also a switching delay at the beginning of each lean period due to the storage of O in the adsorber. This storage delay is used to approximate the delay due to the release of O at the beginning of regeneration and this delay is therefore subtracted from the total delay to determine the amount of delay due to the release of NO alone.
Xiaoguo Tang - Canton MI Joseph Robert Theis - Rockwood MI Robert Jay Natkin - Canton MI Siamak Hashemi - Farmington Hills MI William F. Stockhausen - Northville MI
Assignee:
Ford Global Technologies, LLC - Dearborn MI
International Classification:
F01N 300
US Classification:
60278, 60285, 60297, 123 3, 123DIG 12, 12356819
Abstract:
A hydrogen fueled reciprocating spark ignition engine includes a fuel system for providing gaseous hydrogen to the cylinders of the engine and a lean NOx trap coupled to the engine for treating the engines exhaust. An EGR system provides recirculated exhaust gas to the engine, and a controller operates the fuel system and EGR system during periodic purging of the lean NOx trap such that the engine is operated fuel rich, with the mass of EGR approximating 40%-80% of the mass of air and fuel.
System And Method To Minimize The Amount Of Nox Released From A Nox Trap
Joseph R. Theis - Rockwood MI Gopichandra Surnilla - West Bloomfield MI Justin A. Ura - Livonia MI Hungwen Jen - Troy MI
Assignee:
Ford Global Technologies, LLC - Dearborn MI
International Classification:
F02M 700
US Classification:
123435, 12356811, 123704
Abstract:
A method is described for controlling lean and rich operation of an internal combustion engine coupled to a lean NOx trap. In one example, the termination of the lean air-fuel mixture is based on an oxygen storage capacity and temperature of the NOx trap. In another example, the level and duration of rich air-fuel ratio purging operation is also controlled based on the oxygen storage capacity of the NOx trap.
Bimodal Catalyst-Urea Scr System For Enhanced Nox Conversion And Durability
Clifford Norman Montreuil - Livonia MI, US Joseph Robert Theis - Rockwood MI, US
Assignee:
Ford Global Technologies, LLC - Dearborn MI
International Classification:
B01D 5334
US Classification:
422177, 422171, 422180
Abstract:
The present invention discloses a method for reducing NOin exhaust gases of an internal combustion engine. The purpose of this invention is to convert engine out NO(approximately 90% NO in diesel exhaust) into roughly a 50:50 mixture of NO and NO, while simultaneously oxidizing engine-out hydrocarbons which interfere with the reduction of NOby urea or ammonia. The present invention demonstrates that a 50:50 blend of NO and NOis reduced more rapidly and with higher efficiency than a gas stream which is predominantly NO. In addition, catalyst in an engine exhaust that is a 50:50 mixture of NO and NOis far more resistant to hydrothermal deterioration than using NO alone. In another embodiment of the present invention, a vehicle exhaust system utilizing the method of the present invention is provided.
Xiaoguo Tang - Canton MI, US Joseph Robert Theis - Rockwood MI, US Robert Jay Natkin - Canton MI, US Siamak Hashemi - Farmington Hills MI, US William F. Stockhausen - Northville MI, US
A hydrogen fueled reciprocating spark ignition engine includes a fuel system for providing gaseous hydrogen to the cylinders of the engine and a lean NOx trap coupled to the engine for treating the engine's exhaust. A controller determines when to purge the lean NOx trap and provides gaseous hydrogen to the lean NOx trap during purging by operating the engine fuel rich or injecting hydrogen upstream of the lean NOx trap.
System And Method For Removing Hydrogen Sulfide From An Emissions Stream
Shane Elwart - Ypsilanti MI, US Gopichandra Sumilla - West Bloomfield MI, US Joseph R. Theis - Rockwood MI, US
Assignee:
Ford Global Technologies, LLC - Dearborn MI
International Classification:
F01N 3/00
US Classification:
60285, 60274, 60276, 60277, 60295, 60301
Abstract:
In an apparatus having a combustion engine and an emissions system including a catalytic converter and a metal oxide catalyst disposed downstream of the catalytic converter, a method of controlling a chemical transformation of hydrogen sulfide in an emissions stream to a less-noxious sulfur-containing compound is disclosed. The method includes reacting the hydrogen sulfide with the metal oxide catalyst to form a metal sulfide, monitoring a saturation of the metal oxide catalyst with the metal sulfide, and when a predetermined saturation of metal sulfide on the metal oxide is reached, changing an air/fuel ratio supplied to the combustion engine.
Minimization Of Purge Norelease From Notraps By Optimizing The Oxygen Storage Capacity
Hungwen Jen - Troy MI, US Gopichandra Surnilla - West Bloomfield MI, US Christian Goralski, Jr. - Ypsilanti MI, US Joseph Theis - Rockwood MI, US Justin Ura - Livonia MI, US
The present invention provides a catalyst for use in a NOtrap that has reduced NOrelease during rich purges, increased NO conversion efficiency under stoichiometric conditions, and improved sulfur tolerance. The catalyst of this embodiment includes a precious metal, an oxygen storage component in contact with the precious metal, and a NOstorage material. The oxygen storage component in contact with the precious metal is present in an amount that provides sufficient oxygen storage capacity to reduce the NOrelease from the NOtrap during rich purges to less than 20% of the NOthat is stored in the NOtrap across the operating temperature window of the NOtrap, increase the NOconversion efficiency under stoichiometric conditions to a value greater than 70%, and increase the sulfur tolerance of the NOtrap.
Haren S Gandhi - West Bloomfield MI, US Jun (John) Li - Canton MI, US Joseph Robert Theis - Rockwood MI, US Ronald Gene Hurley - Plymouth MI, US William Lewis Henderson Watkins - Toledo OH, US
A catalyst system to provide emission reductions under lean and stoichiometric conditions. The catalyst system comprises a forward catalyst having a first cerium-free zone including oxides of aluminum, alkali metals and alkaline earth metals and precious metals and a second zone with a lower loading of precious metals, oxides of aluminum, alkali metals or alkaline earth metals. This forward catalyst stores NOx emissions under lean conditions for subsequent reduction and converts HC, CO and NOx during stoichiometric operation. The second downstream catalyst includes precious metals, reduces emissions under stoichiometric conditions, and stores any residual NOx emitted from the first catalyst for subsequent reduction. In another embodiment, a forward catalyst has top and bottom layers designed to reduce emissions under lean conditions. In this embodiment, a second downstream catalyst is used to reduce emissions under stoichiometric conditions.