Timothy W. Birch - Ravenna OH Anthony S. Scheibelhoffer - Norton OH
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
B32B 2730
US Classification:
428517, 428519, 428520
Abstract:
This invention relates to a multilayer thermoformable composite structure including: a formulated cap layer (A) including at least about 50% by weight of a polymethacrylate ester, a polyacrylate ester, copolymers, and/or blends thereof; and a core layer (B) including from about 30% to about 100% by weight of a polyolefin. The multilayer thermoformable structures of the invention are useful in applications requiring the physical properties of an olefin and the gloss, scratch resistance and chemical resistance of an acrylic polymer.
Multilayer Structure With Acrylic Cap Layer, Polyolefin Core Layer, And Intermediate Tie Layer
Anthony S. Scheibelhoffer - Norton OH Timothy W. Birch - Ravenna OH
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
B32B 2730
US Classification:
428517, 428519, 428520
Abstract:
This invention relates to a multilayer thermoformable structure including: (A) a cap layer including at least 50% by weight of a polymethacrylate ester or polyacrylate ester or their copolymers or blends; (B) a core layer including at least 30% by weight polyolefin; and (C) a tie layer intermediate the cap layer (A) and core layer (B). The multilayer thermoformable structures of the invention are useful in applications requiring the physical properties of an olefin and the gloss, scratch resistance and chemical resistance of an acrylic polymer.
Anthony S. Scheibelhoffer - Norton OH Andrew M. Rohn - Clinton OH James T. Kempthorn - Cuyahoga Falls OH Kenneth D. Zabielski - McHenry IL Deenadayalu Chundury - Newburgh IN Timothy W. Birch - Ravenna OH
This invention relates to a solvent based adhesive composition including a major amount of a solvent system and a minor amount of an adhesive polymer system. The solvent system preferably includes a terpene and an aldehyde, ketone, or an aromatic solvent. The adhesive polymer system preferably includes one or a blend of polymers that dissolve, at least in part, in the solvent solution. The components of the solvent adhesive are compatible in that they do not separate upon standing. The solvent based adhesive composition provides good adhesion between polymer articles such as, for example, polyolefin and acrylic films, as well as good adhesion between polymeric articles and wood or metal substrates.
Adhesive Composition Primarily Intended For Use In Medical Applications
Andrew M. Rohn - Clinton OH Anthony S. Scheibelhoffer - Norton OH James T. Kempthorn - Cuyahoga Falls OH Kenneth D. Zabielski - McHenry IL Deenadayalu Chundury - Newburgh IN Timothy W. Birch - Ravenna OH
The present invention provides an adhesive composition for use in bonding a polymeric fitting to an olefin-containing component of an article used in medical applications. The adhesive composition according to the invention includes an adhesive polymer system dissolved in a solvent system. The solvent system includes an organic solvent having a solubility parameter within the range of from about 7. 5 to about 10 (cal/cm ). Subsequent to forming a bond between the polymeric fitting and the olefin-containing component, the adhesive composition can meet the requirements for USP Class VI materials. In a preferred embodiment of the invention, the adhesive composition includes a low shear mixture of an adhesive polymer system including an atactic polypropylene and a low density polyethylene that is dissolved in a solvent system including a blend of d-limonene and a ketone selected from the group consisting of 4-heptanone and cyclohexanone. The adhesive composition can be used, for example, to bond polymeric fittings made of materials such as, but not limited to, acrylic, polycarbonate, polyvinyl chloride, polyolefin, acrylonitrile butadiene-styrene, and polyester, to olefin-containing components of articles used in medical applications such as, but not limited to, tubing.
Polymer Compositions Comprising Polyolefins And Reaction Products Of A Polyolefin And An Unsaturated Carboxylic Reagent And Articles Made Therefrom
Anthony S. Scheibelhoffer - Norton OH, US Deenadayalu Chundury - Newburgh IN, US Gerald W. Drabeck - Akron OH, US Timothy W. Birch - Ravenna OH, US Dennis L. Hammond - Richfield OH, US
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
C08K 3/00
US Classification:
524515, 524425, 524522, 524523
Abstract:
This invention relates to a polymer composition comprising (A) from about 55% to about 75% by weight of at least one polyolefin, (B) from about 2% to about 12% by weight of at least one reaction product of an alpha, beta unsaturated carboxylic reagent and a polyolefin, and (C) from 15% to about 35% by weight of filler. In one aspect, the polymer compositions also include (D) at least one copolymer of ethylene and an olefin, (E) at least one polyamide, or (F) a mixture of (D) and (E). These compositions provide articles and films with improved scratch resistance and hardness. These compositions have improved processing character because their low coefficient of friction.
Polyolefins Compatibilized With Styrene Copolymers And/Or Polymer Blends And Articles Produced Therefrom
Deenadayalu Chundury - North Royalton OH Anthony S. Scheibelhoffer - Norton OH
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
B32B 2708
US Classification:
428517
Abstract:
A compatibilized polymer alloy has been developed which has excellent processability under thermoforming conditions and the molded articles produced from the alloy exhibit superior gloss, shrinkage, surface hardness, polarity, strength and high heat distortion. The alloy is, in general, comprised of a polyolefin composition, a polystyrene copolymer, or polymer blend, and a compatibilizing agent. This polymer composition or alloy is particularly useful in producing packaging materials and food containers.
Low Voc Unsaturated Polyester Systems And Uses Thereof
Anthony S. Scheibelhoffer - Norton OH Gerald W. Drabeck - Akron OH Ronald E. Thompson - Parma OH Dianna B. Dusek - Bedford OH Timothy W. Birch - Ravenna OH Jeffrey L. Wilcoxson - Winonalake IN
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
C08F 800 C08L 6706
US Classification:
525168
Abstract:
This invention relates to a polyester resin comprising (A) from about 5% to about 50% by weight reactive diluent and (B) from about 50% to about 95% by weight of an unsaturated polyester resin prepared from at least one component selected from the group consisting of (i) from about 0. 5% up to about 8% by mole of a polyhydric alcohol, having at least three hydroxyl groups, and at least one transesterification catalyst, (ii) from about 2% up to about 12% by mole of a reaction product of a polyol and a fatty carboxylic acid, and (iii) from about 2% up to about 12% by mole of a fatty reactant selected from the group consisting of a fatty primary alcohol, a fatty epoxide, a fatty monocarboxylic acid and mixtures thereof, wherein each member of the group has up to about 100 carbon atoms. In another aspect, the invention relates to mixtures of the above polyester resins with conventional polyester resins. Methods of reducing volatile organic compound emissions are also part of the invention.
Deenadayalu Chundury - Newburgh IN Anthony S. Scheibelhoffer - Norton OH Berdine L. Leonard - Macedonia OH Ronald E. Thompson - Parma OH Randall S. McAllister - Evansville IN Anthony F. Dean - Cuyahoga Falls OH
Assignee:
Ferro Corporation - Cleveland OH
International Classification:
B32B 2708 C08L 5302
US Classification:
428330
Abstract:
This invention relates to a multilayer thermoformable structure comprising (A) at least one cap layer and (B) at least one core layer, and polymer compositions for making the same. The multilayer structures and polymer compositions of the invention are useful in preparing thermoformed articles and are particularly useful in preparing liners for refrigerators and freezers. The multilayer structures and the polymer composition have good thermoformability and chemical resistance. The multilayer structures and the polymer composition have good surface properties including a glossy finish. Further these materials are compatible with new blowing agents, such as the hydrochlorofluorocarbons and hydrofluorocarbon blowing agents, which are more environmentally friendly. The layers of the multilayer structure do not require a glue layer.
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