Thanh Tri Nguyen - Sugar Land TX, US Tom Eugene Cushman - Humble TX, US John Stevenson - Crosby TX, US Alan Bitzer - Houston TX, US
Assignee:
Fina Technology, Inc. - Houston TX
International Classification:
C08F 2/38 B01J 19/00 B01J 8/18
US Classification:
526 82, 526 83, 526 84, 526 85, 422131, 422139
Abstract:
Disclosed is a method to safely terminate a runaway reaction within a reaction vessel, comprising: sensing an increase in pressure in the reaction vessel, opening a barrier blocking a flow path into the reactor, wherein the barrier opening is achieved via a mechanical response to the sensed increase in pressure, and injecting a kill agent into the reaction vessel via the opened flow path, thereby terminating the reaction. Also disclosed is a system for performing the method. The system functions without an external electrical source and is therefore compliant with ASME standards.
John A. Ewen - Houston TX Alan H. Bitzer - Houston TX
Assignee:
Cosden Technology, Inc. - Dallas TX
International Classification:
C08F 464
US Classification:
502109
Abstract:
A process for pretreating a Ziegler-type catalyst for use in olefin polymerization reactions. An olefin monomer is aded to a fluid carrier stream containing a Ziegler-type catalyst. The carrier stream containing the monomer and the catalyst is passed through an elongated tubular reactor at a flow rate sufficient to provide a residence time in the tubular reactor of less than 1 minute and under temperature conditions to prepolymerize the catalyst within the tubular reactor without plugging of the reactor. In a specific embodiment the residence time within the reactor is no more than 10 seconds, and more particularly, no more than 2 seconds.
John A. Ewen - Houston TX Alan H. Bitzer - Houston TX David L. Gressett - Galena Park TX Herbert G. Hummel - Pasadena TX
Assignee:
Fina Technology, Inc. - Dallas TX
International Classification:
C08F 464
US Classification:
526125
Abstract:
The invention provides a process for increasing the efficiency of pre-polymerized catalysts used in the polymerization of olefins. The invention includes contacting a pre-polymerized catalyst with a cocatalyst or a mixture of cocatalyst and an electron donor prior to introducing the catalyst into a polymerization reaction zone.
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